窯業協會誌
Online ISSN : 1884-2127
Print ISSN : 0009-0255
ISSN-L : 0009-0255
70 巻, 795 号
選択された号の論文の10件中1~10を表示しています
  • 功刀 雅長, 高橋 克明, 沢井 郁太郎
    1962 年 70 巻 795 号 p. 79-86
    発行日: 1962/03/01
    公開日: 2010/04/30
    ジャーナル フリー
    From the results of model experiment convection current of molten glass the authors tried to analyse the flow mathematically and to introduce the experimetl formula on the convection current.
    The temperature of glass in the vertical section at the hot spot ts, the temperature of glass in the descending flow layer near the side wall tw, the thickness of the layer δ, the depth of neutral point Zn, the average velocity of of current at the layer upper than the neutral point vu were formulated as the equation (3), (6), (18) and (14) respectively.
  • 山田 久夫, 木村 脩七
    1962 年 70 巻 795 号 p. 87-93
    発行日: 1962/03/01
    公開日: 2010/04/30
    ジャーナル フリー
    The system Al2O3-SiO2 is studied using co-precipitated gels with pH values in the range 5.0-8.0, obtained by the addition of urea to alcohol solution of mixed siliconethylester and aluminiumethylester.
    Following the combustion of urea between 500°-600°C, the system appears to be amorphous up to about 1000°C. At this temperature an exothermic reaction occurs and a spinel-type phase is formed. It has various amounts of Si4+ substituted with Al3+ in the position of four co-ordination and its lattice parapeter increases as the Al2O3/SiO2 ratio increases.
    Mullite is formed at higher temperatures by the thermal decomposition of the spineltype phase. In the temperature range 1000°-1200°C mullite exhibits two-dimensional grain growth. The exothermic peak of the DTA-curve at about 1200°C is related to the velocity of formation of mullite and at temperatures higher than 1200°C mullite shows a remarkable grain growth. Chemical composition of mullite is not always constant and the possible existence of mullite containing more silica than 3:2 is suggested without saying the existence of the ratio Al2O3/SiO2=3/2-2/1. According to the electron-microscopic studies mullite showed always a needlelike morphology irrespective of the mode of formation.
    It is suggested from the measurement of the lattice spacing that the cristobalite formed in the silica-rich gel has some solid solution of alumina and is different from that produced from silica ge lalone.
  • 高周波用絶縁材料としてのフォルステライト磁器 (第3報)
    杉浦 正敏, 佐野 資郎, 石井 英一, 平井 道雄
    1962 年 70 巻 795 号 p. 93-101
    発行日: 1962/03/01
    公開日: 2010/04/30
    ジャーナル フリー
    It was reported already that the forsterite porcelain containing excess silica has the narrow range of sintering temperatur and the low softening temperature under load, and the present paper concerns with the influence of excess magnesia on the properties.
    A mixture of Mg(OH)2 and SiO2 (α-quartz) corresponding to the molar ratio of 2.2 MgO: 1.0 SiO2 was prepared from the materials of high purity.
    It was heated with the velocity of 200°C/hr., to various temperatures, kept constant for 15 min., and cooled rapidly.
    X-ray analysis was used to identify the minerals in the fired specimens. It was confirmed that the formation of forsterite began at about 1000°C and was completed at 1460°C. The amount of quartz and periclase decreased with temperature; the former disappeared at about 1400°C, while the latter remained even at the highest temperature of the heat treatment. The inversion of quartz occured at 1240°C, but it disappeared at 1460°C.
    The specimen clacined previously at 1460°C and mixed with 5% kaolin could be sintered between 1380°-1500°C.
    By X-ray method only the existence of forsterite was detected from the sintered body. The dielectric loss of this specimen was very small.
    Forsterite porcelains made from sea water magnesia and silicious stone were also studied; six batches having the compositions, MgO 57-70, SiO2 42-30% were calcined until the X-ray proved the termination of the forsterite forming reaction. They were ground and mixed with 5% of kaolin. The sintering temperatures were 1340°-1520°C, increasing with the increase of MgO.
    The coefficient of thermal expansion, the thermal conductivity, and the thermal shock resistance have increased with the increase of MgO- content. The trend of the softening temperature was reflected the relations in the phase diagram. The bending strength became lower with increasing MgO, which presumably came from the effect of the aggregation of forsterite crystals.
    Although X-ray failed to detect the periclase clystals in the specimens containing 58-62% MgO, it is highly probable that the mineral composition are the same with the forsterite porcelain which does not contain excess of MgO.
    These two, however, showed some difference in the properties; especially, the softening temperature under load of the former was considerably higher than that of the latter. Microscopic observation showed that the excess MgO was disolved in the glass matrix, and made the refractive index higher. Moreover, such a texture may be considered as being responsible for the higher softening temperature under load.
    The electrical properties of the specimens made from pure chemical as well as natural raw materials were excellent.
    It was concluded that the forsterite porcelain having the base composition of 58-62% MgO are the best for using as the vacuum tube.
  • 1962 年 70 巻 795 号 p. A9-A12
    発行日: 1962/03/01
    公開日: 2010/04/30
    ジャーナル フリー
  • 内山 辰丙
    1962 年 70 巻 795 号 p. C105-C109
    発行日: 1962/03/01
    公開日: 2010/04/30
    ジャーナル フリー
  • 境野 照雄
    1962 年 70 巻 795 号 p. C110-C118
    発行日: 1962/03/01
    公開日: 2010/04/30
    ジャーナル フリー
  • 1962 年 70 巻 795 号 p. C119-C136
    発行日: 1962/03/01
    公開日: 2010/04/30
    ジャーナル フリー
  • 浜野 健也
    1962 年 70 巻 795 号 p. C137-C139
    発行日: 1962/03/01
    公開日: 2010/04/30
    ジャーナル フリー
  • 素木 洋一
    1962 年 70 巻 795 号 p. C140-C147
    発行日: 1962/03/01
    公開日: 2010/04/30
    ジャーナル フリー
  • 1962 年 70 巻 795 号 p. C153-C156
    発行日: 1962/03/01
    公開日: 2010/04/30
    ジャーナル フリー
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