In our study solid urethane resin was used as binder of stone powder. We studied this artificial stone roll which is combined solid urethane resin, silica sand and feldspar.
The main results obtained are as follows :
(1) Linkage between binder and stone powder is excellent because it is chemical linkage.
(2) Surface-chemical property of roll surface can be changed freely by combining oleophilic urethane resin, hydrophilic feldspar and silice which gets wet in water and oil.
(3) Release property from paper of top press rolls depends on surface-chemical property of roll surface. The best artificial stone roll of release property from paper was made for wood free paper.
(4) According to a series of experiments, we show the new theory about release property from paper.
The new theory is as follows :
The top press roll must not adhere to piling scum and release property of the roll must be excellent.
Granite can satisfy these requirements.
People say that the reason of good release property on granite is based on pinholes of granite.
We deny this theory.
The reasons are as follows :
(1) We observed the surface of granite with a electron microscope. There were a few pinholes on the granite.
(2) Binder has good release property but has not pinholes.
(3) Traditional artificial stone has many pinholes but release property of it is not good. As it cannot resolve pitch trouble, it cannot be used in newspaper machine because stock of newspaper contains pitch.
We think about the reason of good release property on granite as follows :
Pulp stocks contain not only cellulose but also resin as materials and additives. In other words, stocks contain hydrophilic materials and oleophilic materials.
Oleophilic material has good release property against hydrophilic material, and hydrophilic material has good release property against oleophilic material.
Granite consists of mica, silica and feldspar mainly.
Mica is oleophilic material. Silica gets wet in water and oil. Feldspar is hydrophilic material. In other words, granite is the natural composite material. Good hydrophilic and oleophilic balance of granite shows good release property for paper which contains hydrophilic material and oleophilic material.
According to above understanding, we think that there would be the best combination of fillers for each paper.
For example, in the case of wood free paper which contains little pitch, it is good to use oleophilic particles and in the case of newspaper which contains much pitch, it is good to use oleophilic particles mixed with hydrophilic particles.
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