In previous paper the reaction between glucose and ammonia in ammonium sulfite process was reported. Now, it is studied the reaction between wood, which contains hexose, pentose and lignin etc., and ammonia.
In case of cooking of pine with ammonium monosulfite, a appreciable amounts of nitrogen are measured in amphoteric, acidic and alkaline parts as like as in case of cooking of glucose. But, also in a part not absorbable to both cation and anion exchange resins a remarkable amount of nitrogen is observed. It is found that, in the part, there is no neutral substance containing nitrogen, but acids such like that formed in the reactance between glucose and ammonium monosulfite, and ligninsulfonic acid, which is derived from wood and free from nitrogen, are contained there.
The alkaline substances are divided in two parts. The strong alkali is found 4 (5)-methylimidazol which is formed from ammonia and the decomposed substances of glucose. It is presumed, weak alkali and weak acid are also formed by the reaction of decomposed substances of glucose with ammonia and sulfur dioxide etc.
Levoglucosan-6-sulfonic acid, which does not contain nitrogen atom, is extracted from the strong acidic part. From this fact, it seems many sulfonic acids containing nitrogen are formed, keeping the form of carbon of the original sugar.
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