Neutral CF
3 and CF
2 radicals in a hollow cathode DC CF
4 discharge were first detected with a quadrupole mass spectrometer, using the threshold ionization technique. At CF
4 pressure of 27 Pa, the densities of both radicals were measured as a function of discharge current over a range of 20-50 mA. CF
4 pressure dependences of these radical densities were also measured over a CF4 pressure range of 27-80 Pa. The results showed that the CF
3 and CF
2 radical densities increased with discharge current. The CF
3 radical density increased with CF
4 pressure. On the other hand, the CF
2 radical density increased up to 40 Pa and then tended to be decrease.
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