Shinku
Online ISSN : 1880-9413
Print ISSN : 0559-8516
ISSN-L : 0559-8516
Volume 47, Issue 7
Displaying 1-15 of 15 articles from this issue
  • Chiaki HIROSE
    2004 Volume 47 Issue 7 Pages 499-502
    Published: July 20, 2004
    Released on J-STAGE: October 20, 2009
    JOURNAL FREE ACCESS
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  • Akihiro MORITA
    2004 Volume 47 Issue 7 Pages 503-508
    Published: July 20, 2004
    Released on J-STAGE: October 20, 2009
    JOURNAL FREE ACCESS
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  • Takayuki MIYAMAE, Hisakazu NOZOYE
    2004 Volume 47 Issue 7 Pages 509-515
    Published: July 20, 2004
    Released on J-STAGE: October 20, 2009
    JOURNAL FREE ACCESS
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  • Toshifumi IIMORI, Yukio OUCHI, Kazuhiko SEKI
    2004 Volume 47 Issue 7 Pages 516-521
    Published: July 20, 2004
    Released on J-STAGE: January 30, 2010
    JOURNAL FREE ACCESS
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  • Application to Polymer Surfaces for Liquid Crystal Alignment
    Masahito OH-E
    2004 Volume 47 Issue 7 Pages 522-528
    Published: July 20, 2004
    Released on J-STAGE: October 20, 2009
    JOURNAL FREE ACCESS
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  • Kohei UOSAKI, Shen YE
    2004 Volume 47 Issue 7 Pages 529-534
    Published: July 20, 2004
    Released on J-STAGE: October 20, 2009
    JOURNAL FREE ACCESS
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  • Chikaomi OHE, Koichi ITOH
    2004 Volume 47 Issue 7 Pages 535-543
    Published: July 20, 2004
    Released on J-STAGE: October 20, 2009
    JOURNAL FREE ACCESS
    Sum frequency generation (SFG) spectroscopic studies were performed on the structures of the Langmuir-Blodgett monolayers of palmitoyl-L and DL-ornithines (PO) and parmitoyl-L and DL-lysines (PL) on a quartz substrate and those of the monolayers of PO and PL at the air-water interface. The analyses of the SFG spectra based on spectral simulations indicated that (i) the NH groups in the monolayers of L-PO and L-PL on the quartz substrate are more or less parallel to the substrate taking two different orientations of±ca. 30° with respect to the drawing direction of the samples employed by preparation processes, (ii) on increasing the surface pressures of the L-PO and L-PL monolayers at the air-water interface the tilt angles of the CH3 group with respect to the surface normal decreases appreciably, and (iii) the tilt angle of the CH3group in the DL-PL monolayer is appreciably smaller than that of the L-PL monolayer, suggesting the existence of a specific interaction between the L- and D-enantiomers in the DL-PL monolayer at the air-water interface.
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  • Hirokazu UETA, Morihiko SAIDA, Chikara NAKAI, Yoichi YAMADA, Masahiro ...
    2004 Volume 47 Issue 7 Pages 544-549
    Published: July 20, 2004
    Released on J-STAGE: October 20, 2009
    JOURNAL FREE ACCESS
    A combination of a CH4 supersonic molecular beam and a scanning tunneling microscope (STM) has been applied to analyze the formation processes of a monolayer graphite (MG) on a Pt (111) surface. It is found that a full mono-layer develops only when the surface normal component of the CH4 kinetic energy exceeds the threshold much greater than the activation barrier height for the CH4 dissociation on Pt (111). The major cause of the reaction termination below the threshold energy is the enhancement of the activation barrier height due to the reduction of the surface work function, which is resulted from the graphite formation.
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  • Toshihiko YOSHIMURA, Youji YAMASHITA, Kazunori INAMI, Takahiro TSUTSUM ...
    2004 Volume 47 Issue 7 Pages 550-554
    Published: July 20, 2004
    Released on J-STAGE: October 20, 2009
    JOURNAL FREE ACCESS
    The generation of a carbon nanotube was investigated in arc electric discharge in the mixed gas of helium and the atmosphere. A carbon stick and a carbon stick in which lithium is inserted were used for the negative electrode in the arc electric discharge. The carbon stick with litium tends to accelerate the generation of carbon nanotube. It is found that the generation of a carbon nanotube is restricted in the range of atmosphere partial pressure from 10 kPa to 20 kPa and the ideal spherical substance with the size from several hundred nanometers to several micrometers is generated. If the atmosphere partial pressure is lower than those range, the spherical material change into carbon nanotube or carbon fiber.
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  • Hiroaki ITO, Kiyotaka WASA
    2004 Volume 47 Issue 7 Pages 555-561
    Published: July 20, 2004
    Released on J-STAGE: October 20, 2009
    JOURNAL FREE ACCESS
    We have studied on a cold-CO2plasma in a Penning-type rf-glow discharge tube (13.56 MHz) for a gas pressure ranged from 2 to 133 Pa by using optical emission spectroscopy and quadrapole mass spectrometry. It was found that the discharge power to sustain a glow discharge varied with the gas pressure similar to the Paschen's law on a sparking voltage. The minimum rf-power was found at 10Pa. The optical emission spectroscopy and the quadrapole mass spectrometry showed ionization of CO2 was predominant at a low gas pressure region below the minimum discharge gas pressure of 10 Pa. While, the dissociation of CO2 was predominant at a high gas pressure region above the minimum gas pressure of 10 Pa. The addition of H2 into the CO2 plasma in the high gas pressure region produced CnHx such as CH3 and C2H3 at a room temperature. The glow discharge plasma has a potential for a fixing and/or control of CO2 greenhouse gas under a low power consumption.
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  • Motonobu YUKAWA, Shoji IIDA, Takashi EURA
    2004 Volume 47 Issue 7 Pages 562-567
    Published: July 20, 2004
    Released on J-STAGE: January 30, 2010
    JOURNAL FREE ACCESS
    Polycrystalline La1-xCaxMnO3-δ thin film was formed on a Si substrate coated with SiO2 by rf-sputtering in a 100% oxygen atmosphere. A sintered target with almost the same composition as the objective film was used for sputtering. In this study, we analyzed the deposited film's composition, crystallization, specific resistance and temperature coefficient of resistance at room temperature. Results show that the film's composition could be controlled by the target component : when the substrate temperature was high, it was possible to obtain a film with superior crystallization and lower specific resistance. Results also indicate that the temperature coefficient of resistance was influenced little by the substrate temperature.
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  • Toshiyuki ADACHI
    2004 Volume 47 Issue 7 Pages 568-573
    Published: July 20, 2004
    Released on J-STAGE: October 20, 2009
    JOURNAL FREE ACCESS
    Phase formation and diffusion have been investigated in Cu-Si system. Field ion microscope (FIM) and atom-probe field ion microscope (AP-FIM) were used to determine the crystal structures and chemical compositions of the grown phases. From the results of depth profile by AP-FIM, it is proved that the silicide phase take the layer structure of Cu-Si mixture layer and pure Cu layer. The Cu silicide phase estimated was Cu3Si of orthorhombic structure. The orientation relationship of silicide and Si substrate was [111]Cu3Si || [111]Si. The measured value of the diffusion of Cu atoms in Si was four orders in magnitude smaller than the estimated value calculated by the equation of Hall and Racette. Field ion images of Cu atoms in the Cu silicides were dark compared with Si atoms, so that the crystal structures of the Cu silicides have not been determined by FIM.
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  • Yoshinori YAMADA, Satoru IWAMORI, Yasuyuki TAKAHASHI
    2004 Volume 47 Issue 7 Pages 574-580
    Published: July 20, 2004
    Released on J-STAGE: October 20, 2009
    JOURNAL FREE ACCESS
    A frictional durability and mechanical properties of the polytetrafluoroethylene (PTFE) thin films prepared by RF sputtering were estimated by tensile test, and the chemical structures of these films were estimated by x-ray photoelectron spectroscopy (XPS) analysis. The values of the tensile modulus and the breaking strength of the PTFE thin film were 25150 MPa and 545 MPa, respectively. These values were much smaller than those of the bulk PTFE. The mechanical properties of the PTFE thin film were influenced by the heat treatment. Although the tensile modulus and the breaking strength increased with the temperature of the heat treatment, the breaking strain decreased. The breaking strength and the breaking strain decreased with the heat treatment more than 200°C. These results indicate that the excessive cross linking structure in the PTFE thin film due to the heat treatment caused brittleness of the film. Although the frictional durability of the PTFE thin film was increased by the heat treatment within 200°C, it was decreased by the heat treatment at 300°C.
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  • Satoru KANEKO, Kensuke AKIYAMA, Takeshi ITO, Hiroyasu YUASA, Shinji YA ...
    2004 Volume 47 Issue 7 Pages 581-584
    Published: July 20, 2004
    Released on J-STAGE: October 20, 2009
    JOURNAL FREE ACCESS
    The fourth harmonic of Q-switched YAG was used to deposit yttria-stabilized zirconia (YSZ) film on Si(100) substrate. A secondary function generator was employed to modulate Q-switch while the primary generator was synchronized with flash lamps to decrease repetition rate of laser beam. At rate of 2 Hz, beam energy increased50% per pulse. YSZ film was deposited on Si(100) using 3 mol% YSZ sintered pellet and 9 mol% single crystal YSZ as targets. In order to improve crystallinity of YSZ, two-step deposition was also carried out; deposition in oxygen insufficient atmosphere followed by oxygen sufficient atmosphere. The full width at half maxim (FWHM) of rocking curve showed 1.4° for the film produced by two-step deposition on Si substrate with thin SiO2 layer using single crystal YSZ as a target.
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  • Results of the polytetrafluoroethylene tube
    Hiroyuki YOSHIKI, Hiroyuki SHOJI, Yasuhiro HORIIKE
    2004 Volume 47 Issue 7 Pages 585-589
    Published: July 20, 2004
    Released on J-STAGE: October 20, 2009
    JOURNAL FREE ACCESS
    Small size and low-power excited atmospheric-pressure plasma source was proposed and applied to the inner wall modification of a polytetrafluoroethylene (PTFE) tube of φ1 ×0.5 mm. The tube was set between the parallel-plate electrode (2 mm width ×20100 mm long). RF (13.56 MHz) power was supplied to one electrode via a matching network, the other electrode was grounded. The π-type matching network was miniaturized (150 × 100 × 40 mm3) and an inductance L was optimized to satisfy the resonance condition with excitation frequency. He gas was introduced into the tube and exhausted to the air and then the plasma was generated at 25 W and 0.10 l/min1.0 l/min and restricted inside the tube. By rolling up a tube, the successive plasma treatment can be attained. The inner wall of the plasma treated PTFE tube showed the increase of the wettability. The maximum wettability was obtained at a gas flow rate of 0.20 l/min and a plasma treatment time of 15 s. X-ray photoelectron spectroscopy (XPS) of the plasma treated PTFE inner wall revealed an O1s peak at 532 eV corresponding to the C = O group and a hydrocarbon (CH) peak at approximately 285 eV. Scanning electron microscope (SEM) surface pictures showed that the plasma treated PTFE inner wall is smoothed due to the etching effect. It is expected that this technique is easily applicable to enhance biocompatibility for a blood circulating tube.
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