日本接着学会誌
Online ISSN : 2187-4816
Print ISSN : 0916-4812
ISSN-L : 0916-4812
56 巻, 5 号
選択された号の論文の8件中1~8を表示しています
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  • 中村 浩
    2020 年 56 巻 5 号 p. 214-222
    発行日: 2020/05/01
    公開日: 2023/09/27
    ジャーナル フリー

    The manufacture of materials using slurry-based processes, such as the electrodes of Li secondary batteries and fuel cells, can be made more productive by increasing the concentration of the slurry. Shear thickening, which is a particular issue for such highly concentrated slurries for the electrodes of Li secondary batteries, is derived from collisions between particles, it is important to control the size, size distribution, and concentration of the particles, as well as the solvent viscosity. Furthermore, the electrostatic interaction between the particles has a direct impact on shear thickening, and the concentration of salt in the slurry and the particle surface charge are also important characteristics. Since cracks in catalyst layers of a fuel cell affect performance and durability, it is important to obtain the factors that control crack formation. Crack behavior can be controlled by ionomer adsorption into the Pt/carbon in catalyst ink. A well-dispersed catalyst ink produces a homogeneous Pt/carbon and ionomer distribution in the catalyst layers with high fracture toughness, while catalyst inks with a network of agglomerates produce dense aggregates with small primary pores that generate high drying stress.

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  • 仲村 英也, 菅 裕之
    2020 年 56 巻 5 号 p. 190-196
    発行日: 2020/05/01
    公開日: 2023/09/02
    ジャーナル フリー

    In wet granulation processes, a particle adhesion mediated by a liquid bridge is one of the quite important phenomena. In an actual process, the liquid bridge shows dynamic motion due to motion of the particles. Therefore, understanding of a particle-particle adhesion by such a dynamic liquid bridge is an important issue. We have conducted a direct numerical simulation of the particle-particle adhesion by the dynamic pendular liquid bridge. In this review, our recent studies are presented. Firstly, a direct numerical simulation method is briefly explained. Secondly, verification and validation of the direct numerical simulation are presented. Finally, our work, where influence of the wettability of particles on the particle-particle adhesion of colliding particle through droplet was analyzed, is presented.

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  • 高江 恭平, 田中 肇
    2020 年 56 巻 5 号 p. 182-189
    発行日: 2020/05/01
    公開日: 2023/09/02
    ジャーナル フリー

    In colloidal suspensions, electrostatic interactions, hydrodynamic interactions, and their dynamic coupling are of crucial importance both in statics and kinetics of structure formation and rheology, leading to the emergence of various functions of charged soft matter in technological applications and biological cells. From the theoretical and computational viewpoints, however, it has been very challenging to take electrostatic and hydrodynamic interactions into account because both are long-ranged many-body interactions. Another difficulty originates from the fact that the number of charges on colloidal surfaces is determined by chemical equilibrium, and thus, affected by the presence of other colloids or charged surface. Fluid Particle Dynamics (FPD) method is a powerful method to deal with these problems in a physically transparent manner. We here review the concept of the FPD method incorporating the self-organization of colloidal charges - charge regulation. We describe the details of the theoretical formulation to treat long-range electrostatic and hydrodynamic interaction. We also show two computational results where charge regulation becomes relevant as examples. Our method is applicable to more complex problems of charged soft matter systems.

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  • 小林 幹佳, 杉本 卓也
    2020 年 56 巻 5 号 p. 161-171
    発行日: 2020/05/01
    公開日: 2023/09/01
    ジャーナル フリー

    DLVO 理論とゼータ電位による臨界凝集濃度( CCC) の解釈についてまとめた。まず,DLVO 理論について解析解が得られる条件を強調しつつ概説した後,帯電特性の評価に利用される電気泳動とゼータ電位について述べた。次いで,DLVO 理論に基づくCCC の最近の解釈について紹介した。具体的には,CCC は同じイオン価数でもイオン種に依存するが,DLVO 理論とゼータ電位から求めた有効表面電荷密度によりCCC を説明できることを示した。また,CCC が対イオン価数に強く依存するSchulze-Hardy の実験則が,高い表面電位を想定したDLVO 理論により説明できたことは偶然の可能性が高く,低電位を想定したDLVO 理論と有効表面電荷を用いたCCC の解釈がより合理的であることを述べた。さらに,CCC が副イオンの価数に逆比例するという逆Schulze-Hardy 則が実験とDLVO 理論により確認されていることを紹介 した。

総説
  • 石田 尚之
    2020 年 56 巻 5 号 p. 153-160
    発行日: 2020/05/01
    公開日: 2023/09/01
    ジャーナル フリー

    The stability of particle suspensions, which is important in various industrial processes, is generally dominated by the interaction forces between the particles. Understanding the interaction forces between surfaces in liquids is therefore fundamentally important to evaluate and control how particulate matters, including two phase fluids such as emulsions and bubbles, disperse and aggregate in various systems. The invention of the surface force apparatus( SFA) enabled the direct measurement of interaction forces between surfaces in liquids with molecular level resolution has led to remarkable progress in understanding surface forces in detail and the application of atomic force microscopy( AFM) to force measurement has further extended the possibility of force measurements to a broad field of research. This review provides an overview of developments in the investigating of interaction forces between surfaces using SFA and AFM. The properties of various interaction forces are described in detail, particularly focusing on how the nanoscopic structures of various interfaces, including the adsorption structures of solvent and solute molecules and their assemblies to them, play an important role in the interaction forces, between particles.

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