The absorption isotherms of Azoorseillin, Azo Blue (C. I. No.463) and Dianil Azurine G (C. I. No.502) at 90°C, from baths containing 0.05×10
-3, 0.1×10
-3 and 0.5×10
-3 mol dye with varying salt concentration of 0.05_??_3.0 mol NaCl per kg dyeing liquor were determined. The relations between the chemical structure, the aggregating properties of dye ions (N. Ando;
J. Chem. Soc., Japan, 64, 1431 (43″), C. A. 41, 3299e) and the affinity for cotton were studied. The time to obtain each equilibrium absorption of these dyes is longer than for Aizen Direct Blue BBH (C. I. No.406), Diamine Blue 3 B (C. I. No.477) and Nippon Sky Blue (C. I. No.520), and the time required is same for Congo Red (C. I. No.370) and Benzopurpurine 4 BKX (C. I. No.448). The mean standard affinity was calculated by Vickerstaff's method. The values of Congo Red, Benzopurpurine 4 BKX, Azoorseillin, Azo Blue, Dianill Azurine G, Aizen Direct Blue BBH, Diamine Blue 3B, and Nippon Sky Blue were 5.8 Kal, 5.9 Kal, 5.6 Kal, 4.9 Kal, 5.8 Kal, 5.1 Kal, 5.2 Kal and 5.8 Kal, respectively. The effects of the presence of OCH
3, CH
3, OH, NH
2 group in the dye molecule on dyeing property were (1) the hydration of fibre, (2) the hydration of dye, (3) the affinity of dye for cotton, (4) interaction between dye ions in solution. Azoorseillin did not indicate the correlation of aggregation with substantivity.
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