A comparison was made on the pulping characteristics, especially the behavior of hemicelluloses during the cooking in production of paper grade pulps, by means of calcium and sodium base acid sulphite, sodium bisulphite, and two stages sodium base sulphite cooking consisting of the 1st stage bisuiphite and the 2nd acid sulphite cooking. These pulps were made from mixed softwoods (spruce and fir), mixed hardwoods and birch of Hokkaido.
1. In sodium base acid sulphite cooking, the rate of delignification is significantly faster than that with calcium base liquor of the same SO
2 content (Fig. 1). Compared with calcium base unbleached sulphite pulps of the same Sieber number, sodium base sulphite pulps are higher in screened yield (Fig. 2) and degree of polymerisation (Fig. 11), but nearly equal in total yield, brightness (Fig. 12) and polysaccharide composition (Fig. 13).
The rate of hydrolysis of polysaccharides in cooking liquors is greater in calcium base liquor (Fig. 7 and 8), while the amounts of polysaccharides are richer in sodium base liquors when the pulps are obtained at equal delignification (Table 5).
2. In bisulphite cooking, the rate of delignification is so under slower than that in acid sulphite, and considerably longer time at high temperatures (above 155°C) is necessary for production of unbleached pulps poor in lignin. Shortening the times to maximum temperatures (Fig. 3) increases screenings and decreases the screened yield, especially in the cooking at high temperature (165°C), unless penetrating pretreatment (Va-Purge) of chip or disk refining treatment of the cooked chip are carried out. In this process, the decrease of the total yield accompanied by increase of delignification (below 55 of Sieber no.) is greater, especially in hardwood, than that in acid sulphite cooking (Fig. 4).
The amounts of carbohydrates in bisuiphite cooking liquors are significantly poor than those in acid sulphite liquors (Fig. 7 and 8, and Table 5), and it seems that this is due to conversion of most part of carbohydrates dissolved in the bisulphite cooking liquors to sugar sulphonates. A considerable amount of furfural is found too, in the over-cooked bisulphite spent liquors of hardwood (Fig. 9 and 10). The formation of furfural may prevent the delignification. Degree of polymerisation of both softwood and hardwood unbleached bisulphite pulps at low lignin content (below ca. 60 of Sieber no.) is considerably lower than the other pulps at the same Sieber number (Fig. 11). These results show that the bisulphite cooking is not suitable for the production of the unbleached pulps poor in lignin.
When compared at equal total yield, the unbleached bisulphite pulps are superior in brightness and rich in xylan, but remarkably poor in uronic acid.
3. Two stage sulphite cooking of softwood gives a remarkably small amount of screenings even in production of strong unbleached pulps, thus the screened yield increases to 60% (Fig. 6). The unbleached pulps obtained by this process are somewhat superior in brightness, and the content of each polysaccharide is nearly equal to those in normal acid sulphite pulp.
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