繊維学会誌

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Suitable amounts of carboxylate groups can be effectively introduced into cotton fabrics by TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl radical)-mediated oxidation under aqueous conditions such as TEMPO/NaBr/NaClO and TEMPO/Na₂SO₄/NaClO systems. Then, the difference in oxidation mechanism of cotton fabrics between the two TEMPO-oxidation systems in water at pH 9-11 were studied by measuring radical concentration in aqueous reaction solutions using electron spin resonance (ESR) technique. In the case of the conventional TEMPO/NaBr/NaClO system, the obtained ESR results well supported a previously proposed mechanism; NaBrO molecules are immediately formed in situ from NaClO and NaBr, and oxidize almost all TEMPO radicals, present in the reaction solution, to cationic oxoammonium-type compounds, which can in turn oxidize C6-primary hydroxyl groups of cellulose to C6-carboxylate groups. Thus, TEMPO-oxidation behavior of cotton fabrics can be monitored in terms of time-dependent changes in radical concentration of reaction solution using ESR technique. In contrast, most of TEMPO radicals were present in reaction solutions as the original radial structure in the TEMPO/Na₂SO₄/NaClO system, indicating that only a small amount of cationic oxoammonium-type compounds were formed from TEMPO radicals in this system, although this oxidation system also can effectively form carboxylate groups in cotton fabrics. Thus, new oxidation mechanism other than the conventional one is needed to explain the ESR results for oxidation of cotton fabrics in the TEMPO/Na₂SO₄/NaClO system. 4-Acetamido-TEMPO had similar results to those of TEMPO in both oxidation systems.

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A high performance antimicrobial paper was fabricated using a composite pith with bagasse pulp. The composite pith consists of bagasse pith and burned scallop shell particle. Paper prepared using composite pith displayed a larger scallop particle composition than paper prepared that was only mixed with scallop particle. Scallop particles were mainly located on the top surface and, as a result, the functionality was concentrated on the surface of the paper. A slow decline in tensile strength was observed as several hydrogen bonds were forming in spite of the fact that scallop particles inhibit hydrogen bonding.

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Human hairs from Asian female were irradiated with gamma rays up to 25 kGy and the damage to the hairs was investigated. The aspect of hair was unchanged. The moisture adsorption behavior as well as tensile properties for the hairs was also hardly modified within the gamma irradiation level used in this study although the tensile properties for cotton fabrics were seriously degraded. These results suggest that some amino-acid residues in hairs work as radical scavengers. This feature for the keratin protein may be convenient for designing a new functional materials for medical, cosmetic fields which can be sterilized with the gamma irradiation treatment.

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