Surface modification of cellulose and polyester by the oligomeric fluoroalkylating agents having oxime-blocked isocyanate groups was studied by measuring the contact angle, surface free energy, FT-IR(ATR) and XPS spectra. In the case of cellulose, the modified surface changed to oil-repellent. The dispersion components of the surface free energy γ
sd were 21-25mJ/m
2 and the polar components γ
sp were 2-6mJ/m
2 at above 2 wt% of treatment concentration of oligomer solution. There existed a linear relationship between the treatment concentration and the A
C=O/A
C-O peak ratios in FT-IR(ATR). Moreover, the surface free energy decreased with increase in the values of F
1s/O
1s peak area ratios in XPS and became constant above 0.2 of F
1s/O
1s peak area ratios. In the case of polyester, the contact angles of dodecane were 10-30
o and those of water were about 80
o even above 5 wt% of treatment concentration. The values of F
1s/O
1s peak area ratios increased with increase in the treatment concentration and became constant at above 5 wt% of treatment concentration. Based on the FT-IR(ATR) and XPS results, the structures of the modified layer were interpreted in terms of the modification mechanism. In the case of cellulose, the oligomer reacted at the surface, and some parts would diffuse into the inner region. On the other hand, the oligomers were thermally anchored at the polyester surface.
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