繊維学会誌
Online ISSN : 1884-2259
Print ISSN : 0037-9875
58 巻, 7 号
選択された号の論文の10件中1~10を表示しています
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  • 遠田 順, 澤井 大輔, 金元 哲夫, 伊藤 眞義
    原稿種別: 研究論文
    専門分野: 情報学
    2002 年 58 巻 7 号 p. 262-267
    発行日: 2002年
    公開日: 2002/12/31
    ジャーナル フリー
    A film of ultrahigh molecular weight polyethylene reactor powder, prepared by compaction below the melting point, was drawn by two-stage coextrusion at 110-130°C to a total extrusion draw ratio (EDRt) of 24. EDRt is a product of the EDRs of the two stages. Two kinds of flaws were observed; kink bands running at an angle of 30-60° to the fiber axis and periodic variations in the sample thickness along the fiber axis. The effects of extrusion variables on the formation of these flaws were studied by polarized light microscopy, atomic force microscopy (AFM) and wide-angle X-ray diffraction recorded with normal beam (diameter; φ = 0.5mm) and micro-beam (φ = 10 or 100μm). The number of flaws of both types increased with decreasing coextrusion temperature and/or decreasing die EDR used for the second-stage coextrusion. It was found that the kink bands were generated by the spring back associated with the die swell. In contrast, the thickness variation along the draw axis was found to form within an extrusion die during the second-stage draw. The effect of each of the two kinds of flaws on the stress/strain behavior is also discussed.
  • Taiyo Yoshioka, Masaki Tsuji, Yutaka Kawahara, Shinzo Kohjiya, Takeshi ...
    原稿種別: scientific monograph
    専門分野: Infomation Science
    2002 年 58 巻 7 号 p. 268-272
    発行日: 2002年
    公開日: 2002/12/31
    ジャーナル フリー
    The permanganic etching method was applied to various poly(ethylene terephthalate) (PET) fibers having different crystallinity. It turned out for each filament of the PET fibers that the reduction of fiber diameter and the treatment time of etching have a rectilinear relationship between them, as in the case of aqueous alkaline hydrolysis of PET ones. We could express well this rectilinear relationship with a mathematical equation derived from a simple model for etching. A correlation between the apparent rate constant and the amorphous content for as-spun fibers suggested the fact that amorphous portions of PET fiber were preferentially removed by permanganic etching. This fact was confirmed from the evaluation of relative crystallinity of the etched surface region by the microlaser Raman measurement for a given fiber.
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